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Benzothiazole and benzoxazole promoted cleavage of Ru − C(aryl) bond in a four-membered ortho-metalated ruthenium(II) organometallics

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Abstract

The four-membered ruthenium(II) organometallics Ru(η2-RL)(PPh3)2(CO)(Cl) (1) where η2-RL = C6H2O-2-CHNHC6H4R(p)-3-Me-5 and R = CH3 reacts with 2-(2-hydroxyphenyl)benzothiazole (Hhpbt) and 2-(2-hydroxyphenyl)benzoxazole (Hhpbo) in refluxing ethanol to afford Ru(PPh3)2(CO)(hpbt)Cl (2) and Ru(PPh3)2(CO)(hpbo)Cl (3) respectively in excellent yield. In the course of these reactions, the Ru − C(aryl) bond in 1 is cleaved, and the RL ligand is no longer coordinated with the metal center in the products. The spectral (UV–vis, IR, 1H NMR) and electrochemical data of the complexes are reported. The identity of complex 2 has been established by single-crystal X-ray structure determination. The electronic structure and the absorption spectra of the complexes are scrutinized by DFT and TD-DFT analyses. The complexes were also tested for their ability to exhibit DNA-binding activity.

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Acknowledgements

University of Kalyani for infrastructural facilities. The support of DST-FIST to the Department of Chemistry is acknowledged. J. Chowdhury thanks CSIR, India, for the pre-doctoral fellowships.

Funding

Dr. Swarup Chattopadhyay recognizes the financial support provided by the Department of Science and Technology, Government of India (No. SR/S1/IC-65/2010), and the Council of Scientific & Industrial Research, New Delhi, India (No. 01(2898)/17/EMR-II).

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  1. Department of Chemistry, University of Kalyani, Kalyani, Nadia, WB, 741235, India

    Jagannath Chowdhury, Mrinal Kanti Ghosh, Purnananda Garu & Swarup Chattopadhyay

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  1. Jagannath Chowdhury
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Jagannath Chowdhury, Mrinal Kanti Ghosh, Purnananda Garu: Methodology, investigation, writing—original draft preparation. Swarup Chattopadhyay: Conceptualization, review and editing, supervision, funding acquisition, project administration.

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11224_2023_2137_MOESM1_ESM.docx

Supplementary file1 CCDC 2216774 for 2 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via https://www.ccdc.cam.ac.uk/data_request/cif. Supplementary data associated with this article are available in the electronic form at (DOCX 5860 KB)

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Chowdhury, J., Ghosh, M.K., Garu, P. et al. Benzothiazole and benzoxazole promoted cleavage of Ru − C(aryl) bond in a four-membered ortho-metalated ruthenium(II) organometallics. Struct Chem 34, 2039–2050 (2023). https://doi.org/10.1007/s11224-023-02137-9

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