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Synthesis, crystal structure and spectroscopic properties of two new complexes containing azido or dicyanamido bridges

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Abstract

Two new complexes, [Cu(L1){N(CN)2}]·ClO4 (1) (L1 is 1,8-dimethyl-1,3,6,8,10,13-hexa-azacyclotetradecane) and [Co(L2)(N3)2]·ClO4 (2) (L2 is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane) have been synthesized and characterized. The compounds crystallize in the monoclinic system P21 space group for 1 and P21/n for 2. Single crystal X-ray analysis reveals that the compound 1 assumes a one-dimensional structure via hydrogen-bonding interactions, in which each Cu(II) ion is coordinated by four nitrogen atoms from ligand L1 and one nitrogen atom from [N(CN)2]− anion. For compound 2, each Co(III) ion is coordinated by four nitrogen atoms of ligand L2 and two nitrogen atoms from N3 − anion.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (No. 20471031, 90101028, 20331010) and Natural Science Key Foundation of Tian**.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tian**, 300071, P. R. China

    Hui-Bo Zhou, Dai-Zheng Liao, Zong-Hui Jiang, Shi-** Yan & Peng Cheng

  2. The first high school of changsha, Changsha, 410005, Hunan Province, P. R. China

    Hui-Bo Zhou, Li-**n Deng, **g-Zhong Yu, Yang-** Gao & **ao-Fang Yang

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  1. Hui-Bo Zhou
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  2. Dai-Zheng Liao
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  3. Li-**n Deng
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  4. **g-Zhong Yu
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  6. **ao-Fang Yang
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Correspondence to Dai-Zheng Liao.

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Zhou, HB., Liao, DZ., Deng, LX. et al. Synthesis, crystal structure and spectroscopic properties of two new complexes containing azido or dicyanamido bridges. Struct Chem 17, 43–47 (2006). https://doi.org/10.1007/s11224-006-9032-2

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  • DOI: https://doi.org/10.1007/s11224-006-9032-2

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