Abstract
The title complex, [Cu(NiL)2(H2O)2](ClO4)2, has been obtained by self-assembly, where [NiL] is a new macrocyclic oxamido complex ligand. In the crystal, a new kind of supramolecular interaction between the carbon atoms of the oxamido group of each [NiL] complex ligand in a [Cu(NiL)2(H2O)2]2 + cation and the oxygen atom of one of the ester carbonyls of another [Cu(NiL)2(H2O)2]2 + cation, and C—H⋯O, O—H⋯O and π⋯π interactions are observed and link the trinuclear fragments and perchlorate ions to form a 3D supramolecular network.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ribas, J.; Diaz, C.; Costa, R.; Journaux, Y.; Mathoniére, C.; Kahn, O.; Gleizes, A. Inorg. Chem. 1990, 29, 2042.
Tahir, M. N.; Ulku, D.; Atakol, O.; Cakirer, O. Acta Crystallogr. C. 1998, 54, 468.
Gao, E. Q.; Tang, J. K.; Liao, D. Z.; Jiang, Z. H.; Yan, S. P.; Wang, G. L. Inorg. Chem. 2001, 40, 3134.
Arici, C.; Ulku, D.; Tahir, M. N.; Atakol, O. Acta Crystallogr., Sect. E—Struct. Rep. Online 2001, 57, m283.
Li, X.-Z.; Liao, D.-Z.; Jiang, Z.-H.; Yan, S.-P. J. Mol. Struct. 2002, 643, 135.
Tercero, J.; Diaz, C.; Ribas, J.; Maestro, M.; Mahía, J.; Stoeckli-Evans, H. Inorg. Chem. 2003, 42, 3366.
Gao, E.-Q.; Tang, J.-K.; Liao, D.-Z.; Jiang, Z.-H.; Yan, S.-P.; Wang, G.-L. Helv. Chim. Acta 2001, 84, 908.
Christodoulou, D.; Kanatzidis, M.G.; Coucouvanis, D. Inorg. Chem. 1990, 29, 191.
Li, X.-Z.; Yu, L.-H.; Si, S.-F.; Liao, D.-Z.; Jiang, Z.-H.; Yan, S.-P. Inorg. Chem. Commun. 2002, 5, 478.
Campos-Fernandez, C. S.; Clerac, R.; Koomen, J. M.; Russell, D. H.; Dunbar, K. R. J. Am. Chem. Soc. 2001, 123, 773.
Leninger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 882.
Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101, 1629.
Braga, D.; Grepioni, F. Chem. Rev. 1998, 98, 1375.
Hunter, C. A.; Sanders, J. K. M. J. Am. Chem. Soc. 1990, 112, 5525.
Steiner, T. Angew. Chem. Int. Ed. 2002, 41, 48.
Steiner, T.; Saenger, W. J. Am. Chem. Soc. 1992, 114, 10146.
Steiner, T. Chem. Commun. 1997, 727.
Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 3885.
Hunter, C. A. Chem. Soc. Rev. 1994, 101.
Black, D. S. C.; Moss, G. I. Aust. J. Chem. 1987, 40, 129.
Sheldrick, G. M. SHELXS-97 and SHELXL-97, Software for Crystal Structure Analysis; Siemens Analytical X-ray Instruments Inc.: Madison, WI, 1997.
Huheey, J. E. Inorganic Chemistry: Principles of Structure and Reactivity, 3rd edn.; Harper & Row: New York, 1995.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, XZ., Liu, BL., Liao, DZ. et al. Molecular and Supramolecular Structures of a Nickel(II)–Copper(II)–Nickel(II) Trinuclear Complex Containing a New Macrocyclic Oxamido Complex Ligand. Struct Chem 15, 547–551 (2004). https://doi.org/10.1007/s11224-004-0729-9
Issue Date:
DOI: https://doi.org/10.1007/s11224-004-0729-9