Abstract
A new method for the synthesis of thiocyanato- and isothiocyanatoalkyl phenyl sulfides by the reaction of unsaturated compounds with ethyl benzenesulfenate and trimethylsilyl isothiocyanate has been suggested. Regio- and stereoselectivity of the reaction was studied, having taken alkenes, dienes, and alkynes as examples.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1724–1733, September, 2010.
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Zyk, N.V., Gavrilova, A.Y., Mukhina, O.A. et al. Reaction of unsaturated compounds with ethyl benzenesulfenate and trimethylsilyl isothiocyanate. Russ Chem Bull 59, 1771–1780 (2010). https://doi.org/10.1007/s11172-010-0311-0
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DOI: https://doi.org/10.1007/s11172-010-0311-0