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Two 3D Supramolecular Coordination Polymers Constructed from Aromatic Carboxylic Acids and Flexible Bis(thiabendazole) Ligands

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Abstract

Two coordination polymers (CPs), [Zn(L1)(H2bta)] (1) and [Co(L2)(ndc)]·0.75H2O (2), (L1 = 1,6-(thiabendazole)hexane), L2 = 1,3-(thiabendazole)propane, H4bta = 1,2,4,5-benzenetetracarboxylic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized. Single crystal X-ray diffraction analyses reveal that CP 1 and CP 2 feature 1D infinite zigzag and “Ω”-like chains, and further extend into 3D supramolecular framework by O–H⋯O and C–H⋯O hydrogen bonding interactions, respectively. Furthermore, the luminescence properties, thermal stability, and catalytic degradation of methyl orange in a Fenton-like process are also investigated in detail.

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Acknowledgements

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, Tangshan, Hebei, 063009, People’s Republic of China

    **ao-Xue Zhao, Zeng-Chuan Hao, Suo-**a Hou & Guang Hua Cui

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  1. **ao-Xue Zhao
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  2. Zeng-Chuan Hao
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  3. Suo-**a Hou
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  4. Guang Hua Cui
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Correspondence to Guang Hua Cui.

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Zhao, XX., Hao, ZC., Hou, SX. et al. Two 3D Supramolecular Coordination Polymers Constructed from Aromatic Carboxylic Acids and Flexible Bis(thiabendazole) Ligands. J Inorg Organomet Polym 27, 934–940 (2017). https://doi.org/10.1007/s10904-017-0538-4

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