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Iridium–Ruthenium Cluster Complexes with SnPh3 Ligands from the Reaction of IrRu3(CO)13(μ-H) with HSnPh3

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Abstract

The reaction of IrRu3(CO)13(μ-H), 1 with HSnPh3 in hexane solvent at reflux has provided the new mixed metal cluster compounds Ir2Ru2(CO)11(SnPh3)(μ-H)3, 2 and IrRu3(CO)11(SnPh3)3(μ-H)4, 3 containing SnPh3 ligands. Compound 2 which was obtained in low yield (3%) contains one SnPh3, two iridium atoms and two ruthenium atoms. The increase in the number of iridium atoms must have resulted from a metal–metal exchange process. The major product 3 (19% yield) contains an open cluster of one iridium and three ruthenium atoms with three SnPh3 ligands and four hydride ligands. Both compounds were characterized structurally by single crystal X-ray diffraction analysis.

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Acknowledgements

This research was supported by the National Science Foundation under Grant No. CHE-0743190. We wish to thank William C. Pearl, Jr. for assistance with the crystal structure analyses and Johnson Matthey for a donation of RuCl3.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA

    Richard D. Adams, Yuwei Kan, Eszter Trufan & Qiang Zhang

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  1. Richard D. Adams
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  2. Yuwei Kan
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  3. Eszter Trufan
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  4. Qiang Zhang
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Correspondence to Richard D. Adams.

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Dedicated to Professor Malcolm H. Chisholm on the occasion of his 65th birthday.

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Adams, R.D., Kan, Y., Trufan, E. et al. Iridium–Ruthenium Cluster Complexes with SnPh3 Ligands from the Reaction of IrRu3(CO)13(μ-H) with HSnPh3 . J Clust Sci 21, 371–378 (2010). https://doi.org/10.1007/s10876-010-0304-z

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