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Platinum–Ruthenium Cluster Complexes from the Reaction of Ru3(CO)12 with Pt(PBut 3)2

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Abstract

Three new platinum–ruthenium complexes: Pt3Ru3(PBut 3)3(CO)12, 8, Pt5Ru3(PBut 3)3(CO)12, 9 and PtRu3(PBut 3)2(CO)8(μ3-PBut)(μ-H)2, 10 were obtained from the reaction of Ru3(CO)12 with Pt(PBut 3)2. Compound 8 was obtained from this reaction when conducted at 25 °C. Compounds 9 and 10 were obtained when the reaction was conducted at 68 °C. The structure of 8 consists of a central triangular cluster of three ruthenium atoms with one Pt(PBut 3) group bridging each of the three Ru–Ru bonds. The structure of 9 consists of a capped pentagonal bipyramidal cluster of eight metal atoms that is formed formally by the addition of two platinum atoms to 8. The structure of 10 contains a triangular cluster of three ruthenium atoms with a Pt(PBut 3) group bridging one of the Ru–Ru bonds. A t-butyl phosphido ligand formed by degradation of a molecule of PBut 3 bridges the three ruthenium atoms.

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Acknowledgments

This research was supported by the Office of Basic Energy Sciences of the U.S. Department of Energy under Grant No. DE-FG02-00ER14980, and the USC NanoCenter.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA

    Richard D. Adams, Erin M. Boswell, Burjor Captain & Lei Zhu

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  1. Richard D. Adams
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  2. Erin M. Boswell
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  3. Burjor Captain
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  4. Lei Zhu
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Correspondence to Richard D. Adams.

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This report is dedicated to the memory of Professor F. A. Cotton for his many pioneering contributions to inorganic and metal cluster chemistry.

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Adams, R.D., Boswell, E.M., Captain, B. et al. Platinum–Ruthenium Cluster Complexes from the Reaction of Ru3(CO)12 with Pt(PBut 3)2 . J Clust Sci 19, 121–132 (2008). https://doi.org/10.1007/s10876-007-0166-1

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