Abstract
The Bismuth vanadate (BiVO4) nanoparticles were synthesized using the simple sol–gel auto-combustion method. The synthesized BiVO4 NPs showed monoclinic nanostructure in their X-ray diffraction (XRD) pattern. The field emission scanning electron microscopy (FESEM) was used to examine the surface morphology of the synthesized BiVO4 and using energy dispersive X-ray spectroscopy (EDX), the elemental content and purity of the fabricated NPs was verified. Fourier transform infrared spectroscopy (FT-IR) was used to identify the functional groups present on the surface of BiVO4 NPs. The absorption spectra of BiVO4 NPs showed large absorbance in visible region and band gap was found 2.32 eV. The photoluminescence (PL) spectroscopy showed a broadband peak of emission at 578 nm. These BiVO4 NPs also demonstrated supercapacitor characteristics. At a scan rate of 5 mV/s, the maximum specific capacitance was found to be 1160.05 F/g in a 1 M Na2SO4 electrolyte. The BiVO4 samples synthesized for use as supercapacitors have very low resistance and show the good electrochemical performance.
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References
G.Z. Chen, Int. Mater. Rev. 62(4), 173–202 (2017)
S. Huang, X. Zhu, S. Sarkar, Y. Zhao, APL Mater. 7(10), 100901 (2019)
M. Salanne, B. Rotenberg, K. Naoi, K. Kaneko, P.-L. Taberna, C.P. Grey, B. Dunn, P. Simon, Nat. Energy 1(6), 1–10 (2016)
H. Tabassum, C. Zhi, T. Hussain, T. Qiu, W. Aftab, R. Zou, Adv. Energy Mater. 9(39), 1901778 (2019)
Q. Zhang, Z. Zhou, Z. Pan, J. Sun, B. He, Q. Li, T. Zhang, J. Zhao, L. Tang, Z. Zhang, Adv. Sci. 5(12), 1801462 (2018)
W.H. Low, P.S. Khiew, S.S. Lim, C.W. Siong, E.R. Ezeigwe, J. Alloy. Compd. 775, 1324–1356 (2019)
Z.S. Iro, C. Subramani, S. Dash, Int. J. Electrochem. Sci 11(12), 10628–10643 (2016)
G. Zhang, X. **ao, B. Li, P. Gu, H. Xue, H. Pang, J. Mater. Chem. A 5(18), 8155–8186 (2017)
M.A.A.M. Abdah, N.H.N. Azman, S. Kulandaivalu, Y. Sulaiman, Mater. Des. 186, 108199 (2020)
M. Zhi, C. **ang, J. Li, M. Li, N. Wu, Nanoscale 5(1), 72–88 (2013)
H. Liu, X. Liu, S. Wang, H.-K. Liu, L. Li, Energy Storage Mater. 28, 122–145 (2020)
I.P. Swain, S. Pati, S.K. Behera, Chem. Commun. 55(59), 8631–8634 (2019)
T.M. Gür, Energy Environ. Sci. 11(10), 2696–2767 (2018)
W. Lu, J. Shen, P. Zhang, Y. Zhong, Y. Hu, X.W. Lou, Angew. Chem. 131(43), 15587–15593 (2019)
V.K.A. Muniraj, P.K. Dwivedi, P.S. Tamhane, S. Szunerits, R. Boukherroub, M.V. Shelke, ACS Appl. Mater. Interfaces. 11(20), 18349–18360 (2019)
S. Selvam, B. Balamuralitharan, S. Karthick, K. Hemalatha, K. Prabakar, H.-J. Kim, Anal. Methods 8(44), 7937–7943 (2016)
T. Herdt, D. Deckenbach, M. Bruns, J.J. Schneider, Nanoscale 11(2), 598–610 (2019)
W. Bi, E. Jahrman, G. Seidler, J. Wang, G. Gao, G. Wu, M. Atif, M. AlSalhi, G. Cao, ACS Appl. Mater. Interfaces. 11(18), 16647–16655 (2019)
Y. Wang, T. Zhou, K. Jiang, P. Da, Z. Peng, J. Tang, B. Kong, W.B. Cai, Z. Yang, G. Zheng, Adv. Energy Mater. 4(16), 1400696 (2014)
C. Guo, H. Wang, X. Ren, W. Zhang, L. Hou, Y. Wei, Z. Bai, Batteries Supercaps 3(6), 548–556 (2020)
W. Li, T. Luo, C. Yang, X. Yang, S. Yang, B. Cao, Electrochim. Acta 332, 135499 (2020)
C. Yang, F. Lv, Y. Zhang, J. Wen, K. Dong, H. Su, F. Lai, G. Qian, W. Wang, A. Hilger, Adv. Energy Mater. 9(46), 1902674 (2019)
J.B. Lee, J. Moon, O.B. Chae, J.G. Lee, J.H. Ryu, M. Cho, K. Cho, S.M. Oh, Chem. Mater. 28(15), 5314–5320 (2016)
S. Ni, J. Ma, J. Zhang, X. Yang, L. Zhang, Chem. Commun. 51(27), 5880–5882 (2015)
F.K. Butt, M. Tahir, C. Cao, F. Idrees, R. Ahmed, W.S. Khan, Z. Ali, N. Mahmood, M. Tanveer, A. Mahmood, ACS Appl. Mater. Interfaces 6(16), 13635–13641 (2014)
D.P. Dubal, K. Jayaramulu, R. Zboril, R.A. Fischer, P. Gomez-Romero, J. Mater. Chem. A 6(14), 6096–6106 (2018)
P. Nagaraju, A. Alsalme, A. Alswieleh, R. Jayavel, J. Electroanal. Chem. 808, 90–100 (2018)
S. Dutta, S. Pal, S. De, New J. Chem. 42(12), 10161–10166 (2018)
C. Liu, J. Su, J. Zhou, L. Guo, ACS Sustain. Chem. Eng. 4(9), 4492–4497 (2016)
Z.-F. Huang, L. Pan, J.-J. Zou, X. Zhang, L. Wang, Nanoscale 6(23), 14044–14063 (2014)
P. Scherrer, Nachr. Ges. Wiss. Göttingen 26, 98 (1918)
J.I. Langford, A.J.C. Wilson, J. Appl. Cryst. 11, 102 (1978)
W.-H. Lee, J. Kang, H.S. Park, K.M. Nam, S.K. Cho, J. Electroanal. Chem. 838, 172–177 (2019)
Z. He, Y. Shi, C. Gao, L. Wen, J. Chen, S. Song, J. Phys. Chem. C 118(1), 389–398 (2014)
K. Sekar, A. Kassam, Y. Bai, B. Coulson, W. Li, R.E. Douthwaite, K. Sasaki, A.F. Lee, Appl. Mater. Today 22, 100963 (2021)
Y. Li, X. **ao, Z. Ye, Appl. Surf. Sci. 467, 902–911 (2019)
X. Cai, B. Zhang, L. Shi, H. Liu, J. Zhang, L. Huang, S. Tan, Desalin. Water Treat. 57(14), 6365–6371 (2016)
X. Lin, L. Yu, L. Yan, H. Li, Y. Yan, C. Liu, H. Zhai, Solid State Sci. 32, 61–66 (2014)
W.E. Wallace, NIST Chem. Webbook NIST Stand. Ref. Database 69, 20899 (2018)
M.M. Sajid, N. Amin, N.A. Shad, Y. Javed, Z. Zhang, Mater. Sci. Eng., B 242, 83–89 (2019)
Y. **, H. Chen, M. Chen, N. Liu, Q. Li, A.C.S. Appl, Mater. Interfaces 5, 3048–3416 (2013)
Acknowledgements
The authors would like to express their sincere gratitude to the MGV’s LVH College, Panchavati, Nashik, SNJB’s KKHA Arts, SMGL Commerce and SPHJ Science College, Chandwad, Nashik, Savitribai Phule Pune University, Pune, Punjab University, Chandigarh, for providing the technical, instrumental supports. Authors are thankful to the Department of science and technology for providing research facilities under the FIST Programme (Project No.: SR/FIST-415/2018).
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OMP: Conceptualization, Investigation, Writing-original draft. ABG: Investigation, Methodology, GHJ: Investigation, Methodology, BMP: Investigation, Methodology, review and editing AVP: Supervision, Validation, Methodology.
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Pardeshi, O.M., Gite, A.B., Jain, G.H. et al. Sol gel auto-combustion synthesis of bismuth vanadate (BiVO4) nanoparticles and its supercapacitor applications. J Mater Sci: Mater Electron 34, 1817 (2023). https://doi.org/10.1007/s10854-023-11229-5
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DOI: https://doi.org/10.1007/s10854-023-11229-5