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Dual-mode optical thermometry based on La2MgTiO6: Mn4+, Dy3+ double perovskite phosphors

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Abstract

The Mn4+, Dy3+ co-doped La2MgTiO6 phosphors were synthesized by high-temperature solid-phase method. The crystal phase luminescence properties, X-ray photoelectron spectroscopy (XPS) and thermal quenching of phosphors were analyzed. The emission spectra of the Mn4+, Dy3+ co-doped La2MgTiO6 phosphor were shown to exhibit two different emission peaks at 500–550 nm due to the 6H15/2 → 6P7/2 energy level jump of the Dy3+ ion and at 650–750 nm due to the spin-forbidden energy jump 2Eg → 4A2g of Mn4+. The influence of Mn4+, Dy3+ on temperature has different responses to achieve temperature sensing based on fluorescence intensity ratios, and the maximum relative sensitivity is 2.85% K−1 at 448 k in the range 298–498 K. The related results indicate that La2MgTiO6: Mn4+, Dy3+ phosphors have potential applications in optical thermometry.

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The [DATA TYPE] data used to support the findings of this study are available from the corresponding author upon request.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51762010); the Introduced Talents Funds of Guizhou University (No. 2018-59); and the Science Research Found of Guizhou Province, China (Grant No. 2014-7611).

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Authors and Affiliations

  1. Key Laboratory of Functional Composite Materials of Guizhou Province, College of Big Data and Information Engineering, Guizhou University, Guiyang, 550025, Guizhou, China

    Juling Long, Yamin Xu, Weichao Huang & Chaoyong Deng

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  1. Juling Long
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Contributions

CD, WH: Financial support. WH: Suggestion, Guidance. JL: Investigation, Data curation, Data processing, Writing—Original draft preparation. YX: Data curation, Data processing.

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Correspondence to Weichao Huang or Chaoyong Deng.

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Long, J., Xu, Y., Huang, W. et al. Dual-mode optical thermometry based on La2MgTiO6: Mn4+, Dy3+ double perovskite phosphors. J Mater Sci: Mater Electron 34, 1613 (2023). https://doi.org/10.1007/s10854-023-11024-2

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