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Three-dimensional ordered macroporous ceria–lanthanum cobaltate composite as efficient catalyst to activate peroxymonosulfate for N,N-dimethylformamide degradation

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Abstract

In this study, the three-dimensional ordered microporous (3DOM) ceria–lanthanum cobaltate composite (CeO2-3DOM LaCoO3) with peroxymonosulfate (PMS) activation function was prepared by colloidal crystal template method combined with impregnation method. The catalyst has a 3DOM structure with a specific surface area of 67.33 m2 g−1, 8.049 times of LaCoO3 prepared by sol–gel method. CeO2 was uniformly dispersed on the surface of 3DOM LaCoO3. CeO2-3DOM LaCoO3 has an excellent catalytic effect in PMS activation to degrade N, N-Dimethylformamide (DMF). When the DMF initial concentration was 100 mg L−1, the initial pH was 7, the PMS dosage was 2000 mg L−1, and the catalyst dosage was 400 mg L−1, DMF degradation percentage reached 100% in 30 min, and the catalyst maintained high activity over a wide pH range. CeO2-3DOM LaCoO3 still had high activity when it coexists with Ca2+, Mg2+, Cl−, HCO3−, H2PO4− and NO3−. In addition, it has a generally high catalytic degradation efficiency for methylene blue (MB), urotropine (UR), phenol (PH) and bisphenol A (BPA). After a series of characterization, detection and analysis, we proposed a potential mechanism for the CeO2-3DOM LaCoO3/PMS reaction system to degrade DMF and found that singlet oxygen (1O2), sulfate radical (\(SO_{{4}}^{ - } \cdot\)) and hydroxyl radical (·OH) play essential roles in the degradation process. DMF decay followed pseudo-first-order reaction kinetics. The above results suggested that the CeO2-3DOM LaCoO3 would be a promising candidate catalyst for practical wastewater treatment.

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Funding

Shijiazhuang Science and Technology Research and Development Program (211240043A, 191240263A).

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Authors and Affiliations

  1. School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang, 050018, China

    Li Chao, Li Zai-xing, Zhang Qin-qin, Zhang Chen-yang, Yue **n & Ma Wei-Tao

  2. Pollution Prevention Biotechnology Laboratory of Hebei Province, Shijiazhuang, 050018, China

    Li Chao, Li Zai-xing, Zhang Qin-qin, Zhang Chen-yang, Yue **n & Ma Wei-Tao

  3. Tianjushi Engineering Technology Group Co., Ltd., Shijiazhuang, 050011, China

    Chen **ao-fei, **ng Qian & Qi Hao-jie

  4. Shijiazhuang Donghua **long Chemical Co., Ltd., Shijiazhuang, 052165, China

    Tian Zhan-wei

Authors
  1. Li Chao
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  2. Li Zai-xing
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  3. Chen **ao-fei
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  4. Zhang Qin-qin
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  5. Zhang Chen-yang
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  6. Yue **n
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  7. **ng Qian
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  8. Tian Zhan-wei
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  9. Ma Wei-Tao
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  10. Qi Hao-jie
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Corresponding author

Correspondence to Li Zai-xing.

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Handling Editor: Catalin Croitoru.

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Chao, L., Zai-xing, L., **ao-fei, C. et al. Three-dimensional ordered macroporous ceria–lanthanum cobaltate composite as efficient catalyst to activate peroxymonosulfate for N,N-dimethylformamide degradation. J Mater Sci 57, 16280–16300 (2022). https://doi.org/10.1007/s10853-022-07683-x

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