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CO2 capture through electro-conductive adsorbent using physical adsorption system for sustainable development

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Abstract

The most critical energy and environmental challenge that our planet is facing today is to minimize the dependence on fossil fuels. Carbon dioxide may be of utmost significance as a solution of this issue through realization of carbon neutral energy cycle. Potentially, this could be achieved through the carbon dioxide capture as the urgent response to ongoing climate change. Activated carbon (AC) adsorption is one the most effective, environment friendly and techno-economic process for the carbon capture. In the current research, an electro-conductive-activated carbon was prepared by mixing powdered activated carbon (PAC) with an electro-conductive polymer (ECP). Different ratios of 0, 25, 50, 75 and 100 wt% of ECP with PAC were used for the different analyses of activated carbons in a gas mixture of CO2/N2 using a physical adsorption system. Adsorption and desorption analyses, capacities of the process and desorption effects were examined. Electro-conductive polymers (ECP) were mixed with AC samples, where breakthrough time was increased up to 400% when mixed with the PAC for CO2 adsorption. Following adsorption analysis, desorption of activated carbons was conducted with different potentials. It was revealed that mixing could help the PAC sample to overcome the packing issue to increase the breakthrough capacity and the volumes before and after the breakthrough adsorption in the packed bed systems. The desorption rates of the PAC sample were also enhanced, and fast desorption was observed when mixed with ECP. It is envisioned that this method is very much promising carbon capture method for the techno-economic feasibility and sustainable development of the environment.

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Fig. 1

Modified from author’s own experimental set-up

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References

  • Bandosz, T. J. (2006). Activated carbon surfaces in environmental remediation. Amsterdam: Elsevier.

    Google Scholar 

  • Bauer, F., Persson, T., Hulteberg, C., & Tamm, D. (2013). Biogas upgrading: Technology overview, comparison and perspectives for the future. Biofuels, Bioproducts and Biorefining,7(5), 499–511.

    Article  CAS  Google Scholar 

  • Bogusz, A., Oleszczuk, P., & Dobrowolski, R. (2017). Adsorption and desorption of heavy metals by the sewage sludge and biochar-amended soil. Environmental Geochemistry and Health. https://doi.org/10.1007/s10653-017-0036-1.

    Article  Google Scholar 

  • Budhathoki, S., Ajayi, O., Steckel, J. A., & Wilmer, C. E. (2019). High-throughput computational prediction of the cost of carbon capture using mixed matrix membranes. Energy and Environmental Science, 12, 1255–1264.

    Article  CAS  Google Scholar 

  • Choi, H., Piao, J., Woo, N. C., & Cho, H. (2017). Hydrochemical variations in selected geothermal groundwater and carbonated springs in Korea: A baseline study for early detection of CO2 leakage. Environmental Geochemistry and Health,39(1), 109–123.

    Article  CAS  Google Scholar 

  • Derakhshan-Nejad, Z., Sun, J., Yun, S.-T., & Lee, G. (2019). Potential CO2 intrusion in near-surface environments: a review of current research approaches to geochemical processes. Environmental Geochemistry and Health, 1–26.

  • Farooq, M., Almustapha, M., Imran, M., Saeed, M., & Andresen, J. M. (2018). In-situ regeneration of activated carbon with electric potential swing desorption (EPSD) for the H2S removal from biogas. Bioresource Technology,249, 125–131.

    Article  CAS  Google Scholar 

  • Farooq, M., Bell, A. H., Almustapha, M., & Andresen, J. M. (2017). Bio-methane from an-aerobic digestion using activated carbon adsorption. Anaerobe,46, 33–40.

    Article  CAS  Google Scholar 

  • Farooq, M., Chaudhry, I. A., Hussain, S., Ramzan, N., & Ahmed, M. (2012). Biogas upgradation for power generation applications in Pakistan. Journal of Quality and Technology Management, 8(2), 107–118.

    Google Scholar 

  • Farooq, M., Qamar, A., Asim, M., Siddiqui, F., Amjad, M., & Yousaf, A. (2016). Design and analysis of packed bed activated carbon reactor for the enrichment of biogas. University of Engineering and Technology Taxila. Technical Journal,21(1), 58.

    Google Scholar 

  • Jayawardhana, Y., Mayakaduwa, S., Kumarathilaka, P., Gamage, S., & Vithanage, M. (2017). Municipal solid waste-derived biochar for the removal of benzene from landfill leachate. Environmental Geochemistry and Health, 1–15.

  • Kougias, P. G., Treu, L., Benavente, D. P., Boe, K., Campanaro, S., & Angelidaki, I. (2017). Ex-situ biogas upgrading and enhancement in different reactor systems. Bioresource Technology,225, 429–437.

    Article  CAS  Google Scholar 

  • Rajendran, K., Browne, J. D., & Murphy, J. D. (2019). What is the level of incentivisation required for biomethane upgrading technologies with carbon capture and reuse? Renewable Energy,133, 951–963.

    Article  CAS  Google Scholar 

  • Rostami, A., Anbaz, M. A., Gahrooei, H. R. E., Arabloo, M., & Bahadori, A. (2018). Accurate estimation of CO2 adsorption on activated carbon with multi-layer feed-forward neural network (MLFNN) algorithm. Egyptian Journal of Petroleum,27(1), 65–73.

    Article  Google Scholar 

  • Ryckebosch, E., Drouillon, M., & Vervaeren, H. (2011). Techniques for transformation of biogas to biomethane. Biomass and Bioenergy,35(5), 1633–1645.

    Article  CAS  Google Scholar 

  • Saeed, M. A., Farooq, M., Andrews, G. E., Phylaktou, H. N., & Gibbs, B. M. (2019). Ignition sensitivity of different compositional wood pellets and particle size dependence. Journal of Environmental Management,232, 789–795.

    Article  Google Scholar 

  • Scholz, M., Melin, T., & Wessling, M. (2013). Transforming biogas into biomethane using membrane technology. Renewable and Sustainable Energy Reviews,17, 199–212.

    Article  CAS  Google Scholar 

  • Shao, P., Dal-Cin, M., Kumar, A., Li, H., & Singh, D. P. (2012). Design and economics of a hybrid membrane–temperature swing adsorption process for upgrading biogas. Journal of Membrane Science,413, 17–28.

    Article  Google Scholar 

  • Song, C., Liu, Q., Deng, S., Li, H., & Kitamura, Y. (2019). Cryogenic-based CO2 capture technologies: State-of-the-art developments and current challenges. Renewable and Sustainable Energy Reviews,101, 265–278.

    Article  CAS  Google Scholar 

  • Thrän, D., Billig, E., Persson, T., Svensson, M., Daniel-Gromke, J., Ponitka, J., et al. (2014). Biomethane: Status and factors affecting market development and trade. IEA Task 40.

  • Wang, M., Yao, L., Wang, J., Zhang, Z., Qiao, W., Long, D., et al. (2016a). Adsorption and regeneration study of polyethylenimine-impregnated millimeter-sized mesoporous carbon spheres for post-combustion CO2 capture. Applied Energy,168, 282–290.

    Article  CAS  Google Scholar 

  • Wang, T., Yu, W., Liu, F., Fang, M., Farooq, M., & Luo, Z. (2016b). Enhanced CO2 absorption and desorption by monoethanolamine (MEA)-based nanoparticle suspensions. Industrial and Engineering Chemistry Research,55(28), 7830–7838.

    Article  CAS  Google Scholar 

  • Wilberforce, T., Baroutaji, A., Soudan, B., Al-Alami, A. H., & Olabi, A. G. (2019). Outlook of carbon capture technology and challenges. Science of the Total Environment,657, 56–72.

    Article  CAS  Google Scholar 

  • Yang, F., Lee, X., Theng, B. K., Wang, B., Cheng, J., & Wang, Q. (2017). Effect of biochar addition on short-term N2O and CO2 emissions during repeated drying and wetting of an anthropogenic alluvial soil. Environmental Geochemistry and Health,39(3), 635–647.

    Article  CAS  Google Scholar 

  • Zhang, J., **n, Q., Li, X., Yun, M., Xu, R., Wang, S., et al. (2019). Mixed matrix membranes comprising aminosilane-functionalized graphene oxide for enhanced CO2 separation. Journal of Membrane Science,570, 343–354.

    Article  Google Scholar 

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Acknowledgements

M. Farooq indebted to the support of UET Lahore and British Council Pakistan, for providing funding for the research grant. It would be pertinent to mention Ms. Namra Mansoor’s kind cooperation.

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Farooq, M., Saeed, M.A., Imran, M. et al. CO2 capture through electro-conductive adsorbent using physical adsorption system for sustainable development. Environ Geochem Health 42, 1507–1515 (2020). https://doi.org/10.1007/s10653-019-00318-2

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