Abstract
Yarn supercapacitors (YSCs) are attracting considerable interest for wearable electronics and intelligent textiles due to their high flexibility and weavability. In the present study, stainless steel/cotton blended yarns were used as supports and current collectors to produce polypyrrole-coated yarn electrodes. The as-made YSC exhibited a high areal specific capacitance of 344 mF cm−2 at a current density of 0.6 mA cm−2 and good cycling stability (almost 93% capacitance retention over 1000 cycles). Moreover, the YSC could be knitted into other fabrics without damaging its original structure and electrochemical performance owing to its superior flexibility, indicating that it can meet the requirements of energy-storage devices for wearable electronics.
Graphical abstract
![](http://media.springernature.com/lw685/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Figa_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig2_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10570-018-2126-3/MediaObjects/10570_2018_2126_Fig9_HTML.png)
Similar content being viewed by others
References
Alamer FA (2017) A simple method for fabricating highly electrically conductive cotton fabric without metals or nanoparticles, using PEDOT:PSS. J Alloys Compd 702:266–273
Alamer FA (2018) Structural and electrical properties of conductive cotton fabrics coated with the composite polyaniline/carbon black. Cellulose 25:2075–2082
Ambade RB, Ambade SB, Shrestha NK, Salunkhe R, Lee W, Bagde SS, Kim JH, Yamauchi Y, Lee SH, Stadler FJ (2017) Controlled growth of polythiophene nanofibers in TiO2 nanotube arrays for supercapacitor application. J Mater Chem A 5:172–180
Bedeloglu A, Sunter N, Bozkurt Y (2011) Manufacturing and properties of yarns containing metal wires. Mater Manuf Process 26:1378–1382
Bedeloglu A, Sunter N, Yildirim B, Bozkurt Y (2012) Bending and tensile properties of cotton/metal wire complex yarns produced for electromagnetic shielding and conductivity applications. J Text Inst 103:1304–1311
Blinova NV, Stejskala J, Trchová M, Prokeš J, Omastovác M (2007) Polyaniline and polypyrrole: a comparative study of the preparation. Eur Polym J 43:2331–2341
Chen X, Qiu L, Ren J, Guan G, Lin H, Zhang Z, Chen P, Wang Y, Peng H (2013) Novel electric double-layer capacitor with a coaxial fiber structure. Adv Mater 25:6436–6441
Chen Y, Xu B, Wen J, Gong J, Hua T, Kan C-W, Deng J (2018) Design of novel wearable, stretchable, and waterproof cable-type supercapacitors based on high-performance nickel cobalt sulfide-coated etching-annealed yarn electrodes. Small 14:1704373
Dong K, Deng J, Zi Y, Wang YC, Xu C, Zou H, Ding W, Dai Y, Gu B, Sun B (2017) 3D orthogonal woven triboelectric nanogenerator for effective biomechanical energy harvesting and as self-powered active motion sensors. Adv Mater 29:1702648
Fu Y, Ye S, Cai X, Yu X, Kafafy H, Zou D (2013) Integrated power fiber for energy conversion and storage system. Energy Environ Sci 6:805–812
Gao Z, Bumgardner C, Song N, Zhang Y, Li J, Li X (2016) Cotton-textile-enabled flexible self-sustaining power packs via roll-to-roll fabrication. Nat Commun 7:11586
Gholami M, Nia PM, Alias Y (2015) Morphology and electrical properties of electrochemically synthesized pyrrole–formyl pyrrole copolymer. Appl Surf Sci 357:806–813
Girija TC, Sangaranarayanan MV (2006) Polyaniline-based nickel electrodes for electrochemical supercapacitors—influence of Triton X-100. J Power Sources 159:1519–1526
Huang Y, Hu H, Huang Y, Zhu M, Meng W, Liu C, Pei Z, Hao C, Wang Z, Zhi C (2015) From industrially weavable and knittable highly conductive yarns to large wearable energy storage textiles. ACS Nano 9:4766–4775
Jagatheesan K, Ramasamy A, Das A, Basu A (2017) Investigation on shielding and mechanical behavior of carbon/stainless steel hybrid yarn woven fabrics and their composites. J Electron Mater 46:5073–5088
** C, Wang H-T, Liu Y-N, Kang X-H, Liu P, Zhang J-N, ** L-N, Bian S-W, Zhu Q (2018) High-performance yarn electrode materials enhanced by surface modifications of cotton fibers with graphene sheets and polyaniline nanowire arrays for all-solid-state supercapacitors. Eelectrochim Acta 270:205–214
Kou L, Huang T, Zheng B, Han Y, Zhao X, Gopalsamy K, Sun H, Gao C (2014) Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics. Nat Commun 5:3754
Lee JA, Shin MK, Kim SH, Cho HU, Spinks GM, Wallace GG, Lima MD, Lepro X, Kozlov ME, Baughman RH, Kim SJ (2013) Ultrafast charge and discharge biscrolled yarn supercapacitors for textiles and microdevices. Nat Commun 4:1970
Li Y, Sheng K, Yuan W, Shi G (2013) A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide. Chem Commun 49:291–293
Li N, Li X, Yang C, Wang F, Li J, Wang H, Chen C, Liu S, Pan Y, Li D (2016) Fabrication of a flexible free-standing film electrode composed of polypyrrole coated cellulose nanofibers/multi-walled carbon nanotubes composite for supercapacitors. RSC Adv 6:86744–86751
Lin JH, Jhang JC, Lin TA, Huang SY, Chen YS, Lou CW (2017) Manufacturing techniques, mechanical properties, far infrared emissivity, and electromagnetic shielding effectiveness of stainless steel/polyester/bamboo charcoal knits. Fiber Polym 18:597–604
Liu L, Yu Y, Yan C, Li K, Zheng Z (2015) Wearable energy-dense and power-dense supercapacitor yarns enabled by scalable graphene–metallic textile composite electrodes. Nat Commun 6:7620
Lyu X, Su F, Miao M (2016) Two-ply yarn supercapacitor based on carbon nanotube/stainless steel core–sheath yarn electrodes and ionic liquid electrolyte. J Power Sources 307:489–495
Meng Q, Wang K, Guo W, Fang J, Wei Z, She X (2014) Thread-like supercapacitors based on one-step spun nanocomposite yarns. Small 10:3187–3193
Meng Q, Cai K, Chen Y, Chen L (2017) Research progress on conducting polymer based supercapacitor electrode materials. Nano Energy 36:268–285
Müller D, Rambo CR, Recouvreux DOS, Porto LM, Barra GMO (2011) Chemical in situ polymerization of polypyrrole on bacterial cellulose nanofibers. Synth Met 161:106–111
Qu G, Cheng J, Li X, Yuan D, Chen P, Chen X, Wang B, Peng H (2016) A fiber supercapacitor with high energy density based on hollow graphene/conducting polymer fiber electrode. Adv Mater 28:3646–3652
Ren J, Bai W, Guan G, Zhang Y, Peng H (2013) flexible and weaveable capacitor wire based on a carbon nanocomposite fiber. Adv Mater 25:5965–5970
Senthilkumar ST, Wang Y, Huang H (2015) Advances and prospects of fiber supercapacitors. J Mater Chem A 3:20863–20879
Smirnov MA, Sokolova MP, Geydt P, Smirnov NN, Bobrova NV, Toikka AM, Lahderanta E (2017) Dual doped electroactive hydrogelic fibrous mat with high areal capacitance. Mater Lett 199:192–195
Sun J, Huang Y, Fu C, Wang Z, Huang Y, Zhu M, Zhi C, Hu H (2016) High-performance stretchable yarn supercapacitor based on PPy@CNTs@urethane elastic fiber core spun yarn. Nano Energy 27:230–237
VijayaSankar K, KalaiSelvan R (2016) Fabrication of flexible fiber supercapacitor using covalently grafted CoFe2O4/reduced graphene oxide/polyaniline and its electrochemical performances. Electrochim Acta 213:469–481
Wang Y, Yang J, Wang L, Du K, Yin Q (2017) Polypyrrole/graphene/polyaniline ternary nanocomposite with high thermoelectric power factor. ACS Appl Mater Interface 9:20124–20131
Wang H-T, ** C, Liu Y-N, Kang X-H, Bian S-W, Zhu Q (2018a) Cotton yarns modified with three-dimensional metallic Ni conductive network and pseudocapacitive Co–Ni layered double hydroxide nanosheet array as electrode materials for flexible yarn supercapacitors. Eelectrochim Acta 283:1789–1797
Wang H-T, Liu Y-N, Kang X-H, Wang Y-F, Yang S-Y, Bian S-W, Zhu Q (2018b) Flexible hybrid yarn-shaped supercapacitors based on porous nickel cobalt sulfide nanosheet array layers on gold metalized cotton yarns. J Colloid Interface Sci 532:527–535
Wei C, Xu Q, Chen Z, Rao W, Fan L, Yuan Y, Bai Z, Xu J (2017) An all-solid-state yarn supercapacitor using cotton yarn electrodes coated with polypyrrole nanotubes. Carbohydr Polym 169:50–57
**e Y, Wang D (2016) Supercapacitance performance of polypyrrole/titanium nitride/polyaniline coaxial nanotube hybrid. J Alloys Compd 665:323–332
Xu J, Wang D, Yuan Y, Wei W, Gu S, Liu R, Wang X, Liu L, Xu W (2015a) Polypyrrole-coated cotton fabrics for flexible supercapacitor electrodes prepared using CuO nanoparticles as template. Cellulose 22:1355–1363
Xu LL, Guo MX, Liu S, Bian SW (2015b) Graphene/cotton composite fabrics as flexible electrode materials for electrochemical capacitors. RSC Adv 5:25244–25249
Xu R, Wei J, Guo F, Cui X, Zhang T, Zhu H, Wang K, Wu D (2015c) Highly conductive, twistable and bendable polypyrrole–carbon nanotube fiber for efficient supercapacitor electrodes. RSC Adv 5:22015–22021
Xu Q, Fan L, Yuan Y, Wei C, Bai Z, Xu J (2016) All-solid-state yarn supercapacitors based on hierarchically structured bacterial cellulose nanofiber-coated cotton yarns. Cellulose 23:3987–3997
Ye X, Zhou Q, Jia C, Tang Z, Wan Z, Wu X (2016) A knittable fibriform supercapacitor based on natural cotton thread coated with graphene and carbon nanoparticles. Electrochim Acta 206:155–164
Yu D, Goh K, Wang H, Wei L, Jiang W, Zhang Q, Dai L, Chen Y (2014) Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage. Nat Nanotechnol 9:555–562
Yu D, Qian Q, Wei L, Jiang W, Goh K, Wei J, Zhang J, Chen Y (2015) Emergence of fiber supercapacitors. Chem Soc Rev 44:647–662
Zhang D, Miao M, Niu H, Wei Z (2014) Core-spun carbon nanotube yarn supercapacitors for wearable electronic textiles. ACS Nano 8:4571–4579
Zhi J, Reiser O, Wang Y, Hu A (2017) From natural cotton thread to sewable energy dense supercapacitors. Nanoscale 9:6406–6416
Zhou Q, Jia C, Ye X, Tang Z, Wan Z (2016) A knittable fiber-shaped supercapacitor based on natural cotton thread for wearable electronics. J Power Sources 327:363–373
Acknowledgments
This work was supported by the Scientific Innovation Team Project of the Education Department of Hubei Province (No. T201507), Wuhan Science and Technology Bureau (No. 2016010101010016), the Natural Science Foundation of China (No. 51703170) and the National Key Research and Development Program of China (No. 2016YFA0101102). Helpful discussions and suggestions from Prof. Bin Guo (Nan**g Forestry University) were also acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, C., Chen, Z., Rao, W. et al. A high-performance all-solid-state yarn supercapacitor based on polypyrrole-coated stainless steel/cotton blended yarns. Cellulose 26, 1169–1181 (2019). https://doi.org/10.1007/s10570-018-2126-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-018-2126-3