Abstract
The morphology evolution and the corresponding linear viscoelastic behavior of the phase-separating polybutadiene (PB)/low vinyl content polyisoprene (LPI) blend have been investigated by phase contrast optical microscopy (PCOM), small-angle light scattering (SALS) and rheometry. Two kinds of structure evolutions and rheological responses have been observed. It is found that the co-continuous structure generally gives a power law behavior of the dynamic storage modulus versus frequency and the coarsening of co-continuous structure leads to a decrease of the storage modulus. For the droplet-matrix structure, a platform modulus is observed at the mediate frequencies, followed by the typical terminal relaxation behavior of storage modulus at the extremely low frequencies. The decreasing platform modulus and increasing terminal modulus with the growth of droplets are observed and can be well interpreted by the simplified Palierne model. The platform modulus and terminal modulus at a given frequency are found to be scalable with the phase separation time. Besides, the characteristic relaxation time and domain size of the droplets have been obtained by rheology. And it seems that the rheologically determined droplet dimensions are consistent with the ones determined by PCOM and SALS.
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Vinckier, I., Moldenaers, P. and Mewis, J., J. Rheol., 1996, 40: 613
Kim, J.K., Son, H.W., Lee, Y. and Kim, J., J. Polym. Sci. Part A: Polym. Chem., 1999, 37: 889
Zhang, Z.L., Zhang, H.D., Yang, Y.L., Vinckier, I. and Laun, H.M., Macromolecules, 2001, 34: 1416
Li, R.M., Yu, W. and Zhou, C.X., J. Macromol. Sci. Phys., 2006, 45: 889
Vinckier, I. and Laun, H.M., Rheol. Acta, 1999, 38: 274
Polios, I.S., Soliman, M., Lee, C., Gido, S.P., Schmidt-Rohr, K. and Henning Winter, H., Macromolecules, 1997, 30: 4470
Zhang, R., Cheng, H., Zhang, C., Sun, T., Dong, X. and Han, C.C., Macromolecules, 2008, 41: 6818
Niu, Y.H., Yang, L., Shimizu, K., Pathak, J.A., Wang, H. and Wang, Z.G., J. Phys. Chem. B, 2009, 113: 8820
Khademzadeh-Yeganeh, J., Goharpey, F. and Foudazi, R., Macromolecules, 2010, 43: 8670
Yu, W., Zhou, W. and Zhou, C., Polymer, 2010, 51: 2091
Scholz, P., Froelich, D. and Muller, R., J. Rheol., 1989, 33: 481
Palierne, J.F., Rheol. Acta, 1990, 29: 204
Graebling, D., Muller, R. and Palierne, J.F., Macromolecules, 1993, 26: 320
Friedrich, C., Gleinser, W., Korat, E., Maier, D. and Weese, J., J. Rheol., 1995, 39: 1411
Kitade, S., Ichikawa, A., Imura, N., Takahashi, Y. and Noda, I., J. Rheol., 1997, 41: 1039
Jeon, H.S., Nakatani, A.I., Han, C.C. and Colby, R.H., Macromolecules, 2000, 33: 9732
Yu, W., Bousmina, M., Grmela, M. and Zhou, C., J. Rheol., 2002, 46: 1401
Stadler, R., De Lucca Freitas, L., Krieger, V. and Klotz, S., Polymer, 1988, 29: 1643
Mani, S., Malone, M.F. and Winter, H.H., J. Rheol., 1992, 36: 1625
Weis, C., Leukel, J., Borkenstein, K., Maier, D., Gronski, W., Friedrich, C. and Honerkamp, J., Polym. Bull., 1998, 40: 235
Gramespacher, H. and Meissner, J., J. Rheol., 1992, 36: 1127
Bousmina, M., Rheol. Acta, 1999, 38: 73
Krall, A.H., Sengers, J.V. and Hamano, K., Phys. Rev. E, 1993, 48: 357
Li, R.M., Yu, W. and Zhou, C.X., J. Macromol. Sci. Phys., 2007, 46: 1051
Vinckier, I. and Laun, H.M., Macromol. Symp., 2000, 149: 151
**e, R., Liang, H., Yang, B., Jiang, B., Zhang, Q. and Xu, Y., J. Appl. Polym. Sci., 1993, 50: 1397
Zhang, R., Dong, X., Wang, X., Cheng, H. and Han, C.C., Macromolecules, 2009, 42: 2873
Zou, F.S., Dong, X., Liu, W., Yang, J., Lin, D.M., Liang, A.M., Li, W. and Han, C.C., Macromolecules, 2012, 45: 1692
Takeno, H. and Hashimoto, T., J. Chem. Phys., 1998, 108: 1225
Vlassopoulos, D., Rheol. Acta, 1996, 35: 556
Vlassopoulos, D., Koumoutsakos, A., Anastasiadis, S.H., Hatzikiriakos, S.G. and Englezos, P., J. Rheol., 1997, 41: 739
Ajji, A., Choplin, L. and Prud’homme, R.E., J. Polym. Sci. Part B: Polym. Phys., 1991, 29: 1573
Broseta, D., Fredrickson, G.H., Helfand, E. and Leibler, L., Macromolecules, 1990, 23: 132
Mark, J.E., “Physical Properties of Polymer Handbook”, Springer, New York, 2006
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This work was financially supported by the National Natural Science Foundation of China (Nos. 51173195 and 50930002).
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Zou, Fs., Dong, X., Liu, W. et al. Phase behavior actuating morphology and rheological response of polybutadiene/polyisoprene blends under small amplitude oscillatory shear. Chin J Polym Sci 32, 718–730 (2014). https://doi.org/10.1007/s10118-014-1443-8
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DOI: https://doi.org/10.1007/s10118-014-1443-8