Abstract
High performance liquid chromatography (HPLC) has the advantages of rapid analysis and high sensitivity. In the present study a suitable analytical condition has been established for HPLC, and the LAS in modem sediments from core Zhu-9 at the Pearl River mouth has been determined by HPLC. The concentrations of C12-LAS homologues are the highest. The sedimentation flux of C12-LAS was correlated with the average flow of the **jiang and Beijiang rivers: the higher the flow rate, the larger the C12-LAS sedimentation flux. This shows that the more rapidly the river flows, the shorter the LAS will stay in freshwater, the less the extent of biodegradation, the larger the C12-LAS sedimentation flux in the core Zhu-9.
Similar content being viewed by others
References
René, R., Heidi, T., Achim, A. et al., Molecular markers in environmental geochemistry, Washington, DC: American Chemical Society, 1997, 196.
Johannes, T., Manule, H., Maartje, A. T. C. et al., Bioconcentration of LAS: experimental determination and extrapolation to environmental mixtures, Environ. Sci. Technol., 1997, 31: 3426.
de Almeida, J. L. G., Dafaux, M., Ben, T. Y. et al., Linear alkylbenzene, J. Am. Oil. Chemistr. Soc., 1994, 71: 675.
Allen, M. N., Larry, N.B., Charles, E. B. et al., Biodegradation of coproducts of commercial linear alkylbenzene sulfonate, Environ. Sci. Technol., 1997, 31: 3397.
Jean-Marc, A. S., Maekus, M. U., Walter, G., Dynamic behavior of fluorescent whitening agents in greifensee: field measurements combined with mathematical modeling of sedimentation and photolysis, Environ. Sci. Technol., 1998, 32: 1875.
Ding, W. H., Lo, J. H., Tzing, S. H., Determination of linear alkylbenzenesulfonates and their degradation products in water samples by gas chromatography with ion-trap mass spectrometry, Journal of Chromatography A, 1998, 818: 270.
Rapaport, R. A., Eckhof, W. S., Monitoring liner alkylbenzene sulfonate in the environment: 1973–1986, Environ. Toxicol. Chem., 1990, 9: 1245.
Feijitel, T. C., Matthijs, J. E., Rottiers, A. et al., AIS/CESIO environmental surfactant monitoring programme. Part 1: LAS monitoring study in “de Meern” sewage treatment plant and receiving river “Leidsche Rijn”, Chemosphere, 1995, 30: 1053.
Waters, J., Feijtel, T. C. J., AIS/CESIO environmental surfactant monitoring programme: outcome of five national pilot studies on linear alkylbenzene sulphonate (LAS), Chemosphere, 1995, 30: 1939.
Crudden, J. J., Parker, B. A., N-acyl ED3A chelating surfactants: toxicology and irritancy, World Surfactants Congr. 4th., 1996, 3: 52.
Jennifer, A. F., Larry, B.B., Billy, L. M. et al., Fate of alkylbenzenesulfonates and dialkyltetralinsulfonates in sewagecontaminated groundwater, Environ. Sci. Technol., 1992, 26: 1140.
Lin, R. F., Min, Y. S., Wei, K. Q. et al.,210Pb dating of sediment cores from the Pearl River mouth and its environmental geochemistry implication. Geochemistry (in Chinese), 1998, 27: 401.
Hldeshlg, T., Norlo, O., Ryoshl, I., Seasonal variations and modes of riverine input of organic pollutants to the coastal zone: 1. Flux of detergent-derived pollutants to Tokyo Bay, Enviro. Sci. Technol., 1992, 26: 2517.
Eduardo, G. M., Maarten, H., Damia, B. et al., Monitoring long-chain intermediate products from the degradation of linear alkylbenzene sulfonates in the marine environment by solid-phase extraction followed by liquid chromatography/lonspray mass spectrometry, Environ. Sci. Technol., 1997, 31: 504.
Li, W. M., Li, B. J., Investigation of LAS content in river water body in the cities, Science of Environmental Protection (in Chinese), 1998, 24: 26.
Eduardo, G. M., Jesus, M. F., Fate and distribution of linear alkylbenzene sulfonates in the littoral environment, Environ. Sci. Technol., 1998, 32: 1636.
Sun, A. J., Tang, G. L., Huang, R. H., The oscillating characteristics of atmospherical low waves in summer of ENSO/ versa-ENSO years, in Climatology Research—Climate and the Climate of China (ed. Mo, Z. S.), Nan**g: Meteology Publishing House, 1992, 119.
Sun, A. J., Gao, B., Diagnostic research on the characteristics of acute droughts and floods in main wet seasons in the mid-catchment area of the Changjiang River, in Climatology Research—Climate and Environment (ed. Department of Atmology of Nan**g University), Nan**g: Meteology Publishing House, 1998, 73.
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Hu, J., Peng, P., Min, Y. et al. Determination of linear alkylbenzenesulfonates in modern sediments from core Zhu-9 and its significance. Chin. Sci. Bull. 45 (Suppl 1), 80–85 (2000). https://doi.org/10.1007/BF02893790
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02893790