Abstract
We have measured the complete crystalline electric field (CEF) spectrum of Nd3+ in superconducting Nd1·85Ce0·15CuO4 and Nd2CuO3·7F0·3, and in the non-superconducting parent compound, Nd2CuO4, by neutron inelastic scattering. The best description of the ground-state excitations for both compounds is achieved by the addition of a molecular field parameter to the CEF hamiltonian that takes account of exchange interactions from Nd or Cu spin ordering.
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Boothroyd, A.T., Doyle, S.M., McK Paul, D. et al. Crystal field excitations in electron superconductors. Bull. Mater. Sci. 14, 607–611 (1991). https://doi.org/10.1007/BF02744693
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DOI: https://doi.org/10.1007/BF02744693