Abstract
The electrochemical synthesis of δ-fluoroacyl complexes [M]-δ-CORf(M=C5H5(CO)3W or (CO)5Mn; Rf=CF3 or C4F9) was performed according to two procedures: (1) the preliminary electrochemical synthesis of [M]− from [M]2 followed by reaction with a fluorine-containing compound and (2) the electrochemical synthesis of [M]− in the presence of a fluorine-containing compound. Trifluoroacetic anhydride was demonstrated to be the best acylating agent in these reactions. The electrochemical properties of the resulting complexes were studied.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 373–375, February, 2000.
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Denisovich, L.I., Peterleitner, M.G., Stepanov, A.A. et al. Electrochemical synthesis and properties of δ-fluoroacyl and δ-perfluoroalkyl transition metal complexes. Russ Chem Bull 49, 375–377 (2000). https://doi.org/10.1007/BF02494692
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DOI: https://doi.org/10.1007/BF02494692