Abstract
Silica-containing α-zirconium phosphate (α-ZrSiP) was prepared by the precipitation method. X-ray diffractometry was used to characterize α-ZrSiP and to compare it with other α-zirconium phosphates (ZrP). A monoclinic cell with parameters of a=0.9038 nm, b=0.529 nm, c=1.4183 nm and β=91.76° was identified for α-ZrSiP, i.e. silica modifies the original α-ZrP structure. The specific surface area of α-ZrSiP was found to be two orders of magnitude higher then that of α-ZrP.
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References
I.F. Kharpova, E.V. Kazakov,Izvest. Leningr. Univ. Ser. Phys. Chem., 22 (1967) 136.
D. Nauman,Kernenergie, 6 (1993) 173.
C. Konecky, R. Caletka,J. Radioanal. Chem. 14 (1973) 255.
K.U. Barsukova, G.N. Radionova,Radiokhimiya, 14 (1972) 225.
R. Ooms, P. Schonkan, W. Doislagen, L.H. Baetsle, M.D. Hont,J. Inorg. Nucl. Chem., 36 (1974) 665.
Le Van So, L. Szirtes,J. Radioanal. Nucl. Chem., Articles, 99 (1986) 45.
J.B. Goodenough, H.Y.-P. Hong, J.A. Kafalas,Mat. Res. Bull., 11 (1976) 203.
A. Clearfield, S. Pack,J. Inorg. Nucl. Chem., 37 (1975) 1283.
A. Clearfield (ed.), Inorganic Ion Exchange Materials, CRC Press Inc., Boca Raton, Florida, 1982.
L. Szirtes,Solid State Ionics, 61 (1993) 145.
L. Szirtes, K.B. Zaborenko, B.Z. Ioffa, L. Zsinka, Acta Chim. Hung., 54 (1967) 215.
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Szirtes, L., Kuzmann, E. Structural modification of silica-containing α-zirconium phosphate. Journal of Radioanalytical and Nuclear Chemistry Letters 200, 159–167 (1995). https://doi.org/10.1007/BF02163685
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DOI: https://doi.org/10.1007/BF02163685