SpringerLink
Log in

Characteristics of metallic iron in Y-zeolite catalysts reduced by hydrogen atom beams

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Hydrogen atom beams were used to reduce the ionic species of iron-Fe(II) and Fe(III) in Y-zeolite. Reduction to metallic states was confirmed by ferromagnetic resonance (FMR) spectroscopy, and the catalytic activity in CO hydrogenation showed high selectivity towards ethylene and butene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. M. Minachev, Y. I. Isakov:Zeolite Chemistry and Catalysis (A.C.S. Monograph 171), p. 552. American Chemical Society, Washington D.C., 1976.

    Google Scholar 

  2. P. A. Jacobs: inStudies in Surface Science and Catalysis, Vol. 12, p. 71. Elsevier, Amsterdam, 1982.

    Google Scholar 

  3. Kh. M. Minachev, G. V. Antoshin, E. S. Shpiro, Yu. A. Yusofovs: inProc. 6th International Congress on Catalysis, London, 1976, Vol.2, p.621. The Chemical Society, London 1977.

    Google Scholar 

  4. J. B. Uytterhoeven:Acta. Phys. Chem. 24, 53 (1978).

    Google Scholar 

  5. Kh. M. Minachev, G. V. Antoshin, E. S. Shpiro, Yu. A. Yusotev:Application of Zeolite in Catalysis (Eds. G. K. Boreskov and Kh. M. Minachev), p. 153. Akadémiai Kiadó, Budapest, 1979.

    Google Scholar 

  6. Y. Y. Huang, J. R. Andeson:J. Catal.,40, 143 (1975).

    Google Scholar 

  7. Ch. Minachev, V. Kanazirev, L. Kosova, V. Penchev, W. Gunsser, F. Schmidt: inProc. 5th Int. Conf. on Zeolites, p.335, 1980.

  8. J. A. Rabo, C.L. Angell, P.H. Kasai, V. Schomaleer:Disc. Faraday Soc., 329 (1966).

  9. F. Schmidt, W. Gunsser, J. Adolph:Amer. Chem. Soc. Symp. Ser.,40, 291 (1977).

    Google Scholar 

  10. D. Olivier, M. Richard, L. Bonneviot, M. Che:Studies in Surface Science and Catalysis,4, 193 (1980).

    Google Scholar 

  11. J. Novakova, L. Kubelkova, B. Wichterlova, T. Juska, Z. Dolejsek:Zeolites,2, 17 (1982).

    Google Scholar 

  12. B. D. McNiccol, G. T. Pott:J. Catal.,25, 223 (1972).

    Google Scholar 

  13. E. G. Derouane, M. Mestdagh, L. Vielvoye:J. Catal.,33, 169 (1974).

    Google Scholar 

  14. T. Castner, Jr., G. S. Newell, W. C. Holton, C. P. Slichter:J. Chem. Phys.,32, 668 (1960).

    Google Scholar 

  15. P. A. Jacobs: inStudies in Surface Science and Catalysis, Vol. 29, p. 357, Elsevier, Amsterdam, 1986.

    Google Scholar 

  16. F. Hugues, J. A. Dalmon, P. Bussiere, A. K. Smith, J. M. Basset, D. Olivier:J. Phys. Chem.,86, 5136 (1982).

    Google Scholar 

Download references

Author information

Author notes

  1. **-Ho Lee

    Present address: Department of Chemical Engineering, Chungbuk National University, Cheongju, Korea

  2. Dong-Keun Lee

    Present address: Department of Chemical Engineering, Research Institute of Industrial Technology, Gyeongsang National University, Chinju, Korea

Authors and Affiliations

  1. Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, 373-1 Kusong-dong, Yusong-gu, 305-701, Taejon, Korea

    Son-Ki Ihm, **-Ho Lee & Dong-Keun Lee

Authors
  1. Son-Ki Ihm
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. **-Ho Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dong-Keun Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ihm, SK., Lee, JH. & Lee, DK. Characteristics of metallic iron in Y-zeolite catalysts reduced by hydrogen atom beams. React Kinet Catal Lett 57, 301–309 (1996). https://doi.org/10.1007/BF02064744

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02064744

Keywords

Search

Navigation