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DSC-Untersuchungen an Butadien/olefin-CO- und Terpolymeren sowie an ihren Hydrierprodukten

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Abstract

Poly(butadiene-alt-1-olefin) copolymers and poly[(butadiene-alt-ethene)-co-(butadiene-alt-1lefin)] terpolymers, and the hydrogenated products too, has been characterized with the aid of differential scanning calorimetry (DSC). Both the glass transition and the melting behaviour of the partial crystallized products has been investigated. From the peak area the degree of crystallinity has been calculated in a first approximation. The results allow to draw conclusions about the crystallization behaviour in relation to the number and length of the side chains and about the course of the synthesis in question.

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Authors and Affiliations

  1. PCD Polymere Ges. m. b. H., St. Peter Str. 25, A-4021, Linz, Austria

    J. ReuΒner

  2. Sektion Kalorimetrie, UniversitÄt Ulm, Albert-Einstein-Allee 11, D-89069, Ulm

    G. W. H. Höhne

  3. Neuherberg GmbH, Institut für ökologische Chemie, GSF Forschungszentrum für Umwelt und Gesundheit, PF 1129, D-85758, Oberschlei\heim

    H. Utschick

  4. Institut für Technische und Makromolekulare Chemie, Martin-Luther-UniversitÄt Halle-Wittenberg, Schlo\berg 2, D-06108, Halle

    M. Arnold & T. Wegner

  5. Klöckner Dowty GmbH, Capeller Str. 147, D-59368, Werne, Deutschland

    L. Wohlfarth

Authors
  1. J. ReuΒner
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  2. G. W. H. Höhne
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  3. H. Utschick
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  4. M. Arnold
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  5. T. Wegner
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  6. L. Wohlfarth
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Additional information

Herrn Prof. Pr. H.-J. Seifert,Gesamthochschule Kassel, anlÄ\lich seines 65. Geburtstages gewidmet.

Die Autoren bedanken sich sehr herzlich bei Frau Elfi Tewes für die prÄzise Durchführung der zahlreichen DSC-Messungen. Unser Dank gilt auch der Deutschen Forschungsgemeinschaft für die Förderung im Rahmen des SFB 239.

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ReuΒner, J., Höhne, G.W.H., Utschick, H. et al. DSC-Untersuchungen an Butadien/olefin-CO- und Terpolymeren sowie an ihren Hydrierprodukten. Journal of Thermal Analysis 47, 975–992 (1996). https://doi.org/10.1007/BF01979443

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  • DOI: https://doi.org/10.1007/BF01979443

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