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The thermal stabilities of alkali metal alkanoates. Part IV

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Abstract

The thermal stabilities of long-chain lithium and potassiumn-alkanoates from tridecanoate to eicosanoate have been investigated up to 873 K with a MOM derivatograph. The results obtained, together with available data of different kinds, allowed the findings that: (i) in an oxygen atmosphere, stability is limited to crystalline polymorphs; (ii) in nitrogen, the isotropic liquid stability range goes up to 1.3T F /K when the melt forms on fusion of a lithium soap, but has only a narrow extent when the melt forms on clearing of a potassium soap.

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References

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Authors and Affiliations

  1. Centro di Studio per la Termodinamica ed Elettrochimica dei Sistemi Salini Fusi e Solidi del CNR, c/o Institute of Physical Chemistry and Electrochemistry of the University of Pavia, Italy

    P. Ferloni, M. Sanesi, P. Franzosini, T. Meisel & I. Lányi

  2. Institute for General and Analytical Chemistry, Technical University of Budapest, Hungary

    T. Meisel & I. Lányi

Authors
  1. P. Ferloni
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  2. M. Sanesi
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  3. P. Franzosini
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  4. T. Meisel
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  5. I. Lányi
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Additional information

One of us (P. Ferloni) gratefully acknowledges a financial contribution jointly supplied by the Hungarian Academy of Sciences and the Italian National Research Council.

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Ferloni, P., Sanesi, M., Franzosini, P. et al. The thermal stabilities of alkali metal alkanoates. Part IV. Journal of Thermal Analysis 22, 137–143 (1981). https://doi.org/10.1007/BF01915706

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  • DOI: https://doi.org/10.1007/BF01915706

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