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Atranes. V. Proton magnetic resonance spectra of organyl and organoxysilatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The proton magnetic resonance spectra of eight organyl- and organoxysilatranes,

(R = CH3, C2H5, i-C3H7, CH2=CH, C6H5, CH3O, C2H5O, n-C3H7O) are investigated. The PMR resonance signals are interpreted, taking into account magnetic anisotropy of substituents and dπ-pπ interaction effects. The present communication gives results of proton magnetic resonance (PMR) studies of organyl- and organoxysilatranes (I). The table shows the compounds studied and the chemical shifts of the magneto-equivalent groups of protons in their spectra (see figure).

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References

  1. M. G. Voronokov, and G. I. Zelchan, KhGS, 210, 1965.

  2. M. G. Voronokov, I. B. Mazheika, and G. I. Zelchan, KhGS, 58, 1965.

  3. Ya. Ya. Baltkais, M. G. Voronkov, and G. I. Zelchan, Izv. AN LatvSSR, no. 2, 102, 1964.

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  4. M. G. Voronkov, and G. I. Zelchan, KhGS, 51, 1965.

  5. NMR Spectra Catalog. Varian Associates, N. Y., 1962.

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Authors and Affiliations

  1. Scientific Research Institute of Chemistry, Lobachevskii Gor'kii State University, Institute of Organic Synthesis AS Latvian SSR, Riga

    A. N. Egorochkin, V. A. Pestunovich, M. G. Voronkov & G. I. Zelchan

Authors
  1. A. N. Egorochkin
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  2. V. A. Pestunovich
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  3. M. G. Voronkov
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  4. G. I. Zelchan
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Additional information

For part IV see [1].

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Egorochkin, A.N., Pestunovich, V.A., Voronkov, M.G. et al. Atranes. V. Proton magnetic resonance spectra of organyl and organoxysilatranes. Chem Heterocycl Compd 1, 198–200 (1965). https://doi.org/10.1007/BF01046689

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  • DOI: https://doi.org/10.1007/BF01046689

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