Summary
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1.
A flowsheet is proposed for the processing of kerosine-gas oil fractions from high-sulfur petroleums, which provides for the possibility of producing various chemical and fuel products by solvent extraction and hydrogenation.
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2.
It is shown that aromatized fractions which are suitable for the production of aromatic hydrocarbons by hydrogenation, as well as low-sulfur components for Diesel fuel, may be obtained from kerosine-gas oil fractions by extraction with selective solvents.
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3.
By hydrorefining extracts under a hydrogen pressure of 40 atm the feedstock is extensively desulfurized and the bicyclic aromatic hydrocarbons are partially hydrogenated, this being accompanied by the formation of low-boiling fractions and a lowering of the boiling point of the liquid products.
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4.
By the high-temperature hydrogenation of the hydrorefined extracts, monocyclic aromatic C6–C10 hydrocarbons, naphthalene and other hydrocarbons are produced, the relative content of individual hydrocarbons and their concentrations in narrow hydrogenate fractions being controllable by varying the extent of the hydrodealkylation reaction and the decomposition of the standard hydrocarbons.
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Literature cited
Advances in Petroleum Chemistry and Refining, Vol. 4, IL (1963), pp. 242, 243.
E. G. Ivchenko and G. V. Sevast'yanova, Sulfur and High-Sulfur Petroleums of Bashkiria, Gostoptekhizdat (1963).
G. V. Sevast'yanova and E. G. Ivchenko, Sulfur Petroleums and Products from Processing Them, No. IV, Gostoptekhizdat (1963), p. 68.
G. F. Pal'chikov, A. I. Mezhlumova, A. A. Krichko, et al., Khim i tekhnol. topliv i masel, No. 11 (1962).
I. Treubel, W. Schneider, and H. Rosner, Chem. Techn.,15, 11, 688 (1963).
Yu. F. Sokov and Z. D. Putilova, Author's certificate No. 142627, 1961. Byull. izobr., No. 22 (1961).
A. I. Gully and W. P. Ballard, Advances in Petroleum Chemistry and Refining, Vol. 7, New York-London (1963), p. 241.
A. A. Krichko, A. V. Lozovoi, et al., Neftepererabotka i neftekhimiya, No. 10 (1962).
B. Natori and M. De Malde, Hydrocarbon Process and Petrol. Ref., Vol. 43, No. 12 (1964), p. 91.
A. A. Krichko and L. S. Sovetova, Collection: Chemical Processing of Tars, Izd. Nauka (1965), p. 87.
A. V. Topchiev, G. M. Mamedaliev, et al., DAN SSSR,112, 6, 1071 (1957).
A. V. Topchiev and G. M. Mamedaliev, DAN SSSR,117, 6, 1007 (1957).
V. V. Sredin, Neftepererabotka i neftekhimiya, No. 4 (1964).
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N. G. Zubarev, K. M. Masagutova, L. S. Sovetova, T. M. Ravikovich, and V. F. Cherkasova participated in the experimental work.
Translated from Khimiya i Teknologiya Toptiv i Masel, No. 11, pp. 9–13, November, 1966.
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Éigenson, A.S., Krichko, A.A., Kozik, B.L. et al. Production of aromatic hydrocarbons from kerosine-gas oil fractions from sulfur crudes. Chem Technol Fuels Oils 2, 746–750 (1966). https://doi.org/10.1007/BF00718872
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DOI: https://doi.org/10.1007/BF00718872