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Correlation between transport and equilibrium properties through the ternary interaction parameter for cosolvent and cononsolvent polymeric systems

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Abstract

A study of the ternary polymer systems dimethyl formamide-ethyl acetate-polystyrene, chloroform-1,4 dioxane-polystyrene and tetrahydrofuran-chloroform-polystyrene was carried out by viscosity and light scattering at 298 K. A good correlation has been found between the excess intrinsic viscosity, unperturbed polymer dimensions, second virial coefficient and the excess Gibbs free energy by using a ternary interaction parameter, dependent on molecular weight. This modification enables the conversion between transport and equilibrium properties.

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Author notes

  1. A. Campos

    Present address: Departament de Química Física, Universitat de Valencia, Burjassot, 46100, Valencia, Spain

Authors and Affiliations

  1. Departament de Química Física, Universitat de Valencia, Burjassot, 46100, Valencia, Spain

    V. Soria

  2. Cranfield Institute of Technology, Cranfield, Bedford, England

    C. M. Gómez

Authors
  1. C. M. Gómez
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  2. V. Soria
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  3. A. Campos
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Gómez, C.M., Soria, V. & Campos, A. Correlation between transport and equilibrium properties through the ternary interaction parameter for cosolvent and cononsolvent polymeric systems. Colloid Polym Sci 270, 197–206 (1992). https://doi.org/10.1007/BF00655470

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  • DOI: https://doi.org/10.1007/BF00655470

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