Abstract
Stevens rearrangement of the benzyl bromides of benzo[b]-1,4-diazabicyclo[2.2.2]octene and benzo[f]-1,5-diazabicyclo[3.2.2]-nonene occurs with expansion of the diazabicyclic fragments to form a mixture of stereoisomers. Both the ethylene and the trimethylene bridges participate in the rearrangement of the nonene.
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For Communication 27 see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 383–387, March, 1993.
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Doronina, S.O., Gall', A.A., Mamatyuk, V.I. et al. Diazabicycloalkanes with bridgehead nitrogen atoms. 28. Stevens rearrangement of benzodiazabicycloalkenes. Chem Heterocycl Compd 29, 321–324 (1993). https://doi.org/10.1007/BF00531509
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DOI: https://doi.org/10.1007/BF00531509