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Diazabicycloalkanes with bridgehead nitrogen atoms. 28. Stevens rearrangement of benzodiazabicycloalkenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Stevens rearrangement of the benzyl bromides of benzo[b]-1,4-diazabicyclo[2.2.2]octene and benzo[f]-1,5-diazabicyclo[3.2.2]-nonene occurs with expansion of the diazabicyclic fragments to form a mixture of stereoisomers. Both the ethylene and the trimethylene bridges participate in the rearrangement of the nonene.

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References

  1. A. A. Gall', V. N. Sil'nikov, and G. V. Shishkin, Khim. Geterotsikl. Soedin., No. 8, 1095 (1992).

    Google Scholar 

  2. V. I. Vysochin and G. V. Sishkin, Khim. Geterotsikl. Soedin., No. 5, 664 (1985).

    Google Scholar 

  3. S. H. Pine, J. Cheney, B. Catto, and J. D. Petersen, J. Org. Chem., 39, 130 (1974).

    Google Scholar 

  4. N. P. Luk'yanchuk, N. I. Sagalaeva, V. K. Soboleva, and G. V. Shishkin, Khim. Geterotsikl. Soedin., No. 7, 966 (1987).

    Google Scholar 

  5. G. E. Sal'nikov, A. A. Gall', and G. V. Shishkin, Khim. Geterotsikl. Soedin., No. 10, 1402 (1991).

    Google Scholar 

  6. N. P. Luk'yanchuk, V. N. Sil'nikov, and G. V. Shishkin, Khim. Geterotsikl. Soedin., No. 8, 1106 (1989).

    Google Scholar 

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For Communication 27 see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 383–387, March, 1993.

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Doronina, S.O., Gall', A.A., Mamatyuk, V.I. et al. Diazabicycloalkanes with bridgehead nitrogen atoms. 28. Stevens rearrangement of benzodiazabicycloalkenes. Chem Heterocycl Compd 29, 321–324 (1993). https://doi.org/10.1007/BF00531509

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  • DOI: https://doi.org/10.1007/BF00531509

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