This is a preview of subscription content, log in via an institution to check access.
Literature cited
I. B. Bersuker, “On the theory of the elementary act in catalysis,” Kinet. Katal., 18, No. 5, 1268–1282 (1977).
I. B. Bersuker, “Vibronic facts in the catalytic fixation of nitrogen,” Teor. Éksp. Khim., 14, No. 1, 3–12 (1978).
I. B. Bersuker, “Mutual vibronic influence of weakly coordinated molecular systems in chemical reactions and catalysis,” Chem. Phys., 31, No. 9, 85–93 (1978).
I. B. Bersuker, “Modern aspects of structure/reactivity problems for coordination compounds, ” in: Coordination Chemistry-20. Pergamon Press, Oxford-New York (1980), pp. 201–218.
I. B. Bersuker, S. S. Budnikov, and A. S. Dimoglo, “Vibronic theory of the activation of carbon monoxide and nitric oxide during coordination,” Kinet. Katal., 23, No. 6, 1454–1460 (1982).
Yu. Ya, Kharitonov and O. V. Basileva, “Empirical relationships between several molecular constants of carbon-oxygen bonds,” Zh. Neorg. Khim., 23, No. 4, 867–875 (1978).
A. A. Radtsig and B. M. Smirnov, Handbook of Atomic and Molecular Physics [in Russian], Atomizdat, Moscow (1980).
S. G. Gagarin, “Estimation of the orbital vibronic constants of diatomic molecules,” Koord. Khim., 6, No. 2, 215–220 (1980).
N. S. Hush and M. L. Williams, Carbon monoxide bond length, force constant, and infrared intensity vibrations in strong electric fields: valence shell calculation with applications to properties of adsorbed and complexed CO,” J. Mol. Spectrosc., 50, Nos. 1–3, 349–368 (1974).
R. S. Nyholm, “Tilden Lecture: electron configuration and structure of transitionmetal complexes,” Proc. Chem. Soc., No. 8, 273–296 (1961).
C. W. F. T. Pistoriua, and P. C. Haarhoff, “Normal coordinate treatment and force constant of some group VI hexacarbonyls,” J. Mol. Spectrosc., 3, No. 6, 621–631 (1959).
L. F. Dahl and R. E. Rundle, “The crystal structure of dimanganese decacarbonyl, Mn2(CO)10,“ Acta Crystallogr., 16, No. 5, 419–426 (1963).
N. Flitcroft, D. K. Huggins, and H. D. Kaesz, “Infrared spectra of (CO)5Mn-Re(CO)5 and the carbonyls of manganese, technetium, and rhenium; assignments of C=O and M=C stretching absorptions,” Inorg. Chem., 3, No. 8, 1123–1130 (1964).
M. R. Churchill and B. G. de Boer, “Structural studies on polynuclear osmium carbonyl hydrides. 1. Crystal structures of the isomorphous species H2Os3(CO)11 and Os(CO)12. Direct information on the role of an equatorial μ2-bridging hydride ligand in perturbing the arrangement of carbonyl ligands in triangular cluster,” Inorg. Chem., 16, No. 4, 878–884 (1977).
G. A. Battiston, G. Bor, U. K. Dietler, et al., “Comparative infrared and Raman spectroscopic β(CO) study of Ru3(CO)12, Os3(CO)12, their mixed crystals, and mixed triangular cluster carbonyls Ru2Os(CO)12 and RuOs2(CO)12,” Inorg. Chem., 19, No. 7, 1961–1973 (1980).
G. G. Summer, H. P. Rlug, and L. E. Alexander, “The crystal structure of dicobalt octacarbonyl,” Acta Crystallogr., 17, No. 6, 732–742 (1964).
G. Bor, “Effect of the bridging ligands on the stretching force constants of the compounds Co2(CO)6(μ-Y)2 and Fe2(CO)6 (μ-X)2 (where Y = CO, P, As, CR and X = S, SR, Se, PRR', Br, I),” J. Organomet. Chem., 94, No. 2, 181–188 (1975).
A. N. Nesmeyanov, G. G. Dvoryantseva, Yu. N. Sheinker, et al., “Frequencies and integral intensities of the stretching vibrations of carbonyl groups in the IR spectra of cyclopentadienyl complexes of mixed metal carbonyls,” Dokl. Akad. Nauk SSSR, 169, No. 4, 843–846 (1966).
E. R. Corey, L. F. Dahl, and W. Besk, “Rh6(CO)16 and its identity with previously reported Rh4(CO)11,” J. Am. Chem. Soc., 85, No. 8, 1202–1203 (1963).
A. K. Smith, F., Hughes, A. Theolier, et al., “Surface-supported metal cluster carbonyls. Chemisorption, decomposition and reactivity of Rh6(CO)16 supported on alumina, silica-alumina, and magnesia,” Inorg. Chem., 18, No. 11, 3104–3112 (1979).
Kh. Missner and D. V. Korol'kov, “Electronic structure of binuclear carbonyls Mn2(CO)10, Tc2(CO)10, and Re2(CO)10,” Zh. Strukt. Khim., 13, No. 4, 689–700 (1972).
D. V. Korolkov and H. Miessner, “Elektronenstruktur und Natur der chemischen Bindung in Carbonyl-Cluster-Verbindungen von Übergangsmettallen,” Z. Phys. Chem., 253, Nos. 1–2, 25–32 (1973).
V. T. Aleksanyan and B. V. Lokshin, the Vibrational Spectra of π-Complexes of Transition Metals [in Russian], Moscow (1976) (Itogi Nauki i Tekhniki (VINITI), Ser. Stroenie Molekul i Khim. Svyaz', Vol. 5).
Author information
Authors and Affiliations
Additional information
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 18, No. 6, pp. 694–699, November–December, 1982.
Rights and permissions
About this article
Cite this article
Svitin, A.P., Budnikov, S.S., Bersuker, I.B. et al. Vibronic activation of the CO molecule in transition-metal clusters in the one-parameter approximation. Theor Exp Chem 18, 637–642 (1983). https://doi.org/10.1007/BF00516964
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00516964