Summary
New compounds of formula [AuL(PMe3)]Cl [L = imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by elemental analysis, and i.r., 13C- and 31P-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to AuI compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.
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Akhtar, M.N., Isab, A.A., Hussain, M.S. et al. Synthesis of thionato(trimethylphosphine)gold(I) complexes. Transition Met Chem 21, 553–555 (1996). https://doi.org/10.1007/BF00229711
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DOI: https://doi.org/10.1007/BF00229711